Max working load is probably more a function of the bearings than the strength of the block as a whole. The balls would squish and jam up or break before the block explodes.
As for working out the loads, multiply how much you can physically lift with the rope by the purchase you intend to use and that will give you a reasonable estimate of the applicable loads that are possible.
eg. 30kg x 7 = 210kg, a 650kg working load has a factor of safety of 650/210 = 3.1, this should be enough for unexpected peak loads.