The Pylons are sealed with closed cell foam plugs, that start flush at the top and extend downward past the bolt holes. The front pylons have a small vent tube through the center of the foam plug to release any pressure in the hulls. Of course the foam begins to disintegrate with age, and If you are picking up water from the pylons it's most likely around the holes for the corner casting bolts. I've never heard of a replacement plug being available??
The foam plugs are exposed to the elements at two places per pylon. At the top of the pylon and at the bolt holes. The two problems with using a sealant to cover exposed areas are, the vent tubes in the top of the front pylon, and the bolt holes, that need to be left cleanly open somehow.
A drinking straw could be placed over the vent tube to keep the tube clear as silicon is smeared over the top of the pylon. A dowel or maybe the bolts themselves wrapped in wax paper or cellophane could be placed in the bolt holes after silicon is smeared or somehow inserted into the holes, and given time to dry. Then when the bolts are pulled free of the pylon, the dried silicon left behind helps seal the foam from the elements but leaves the hole free and clear for the bolt.
If the trampoline is tight the frame will require more work with a rubber mallet to get off but should pull away. Just depends on how tight the fit between pylons and corner casting have become, including and any built up crud or heaven forbid, epoxy.