Been working with gelcoat recently. What is your anticipated project?
Of course, the key to success in any project with fiberglass/ gelcoat is (1) surface prep, (2) practice, and (3) elbow grease.
For small stuff (patches, ding repair, etc), gelcoat is easy to apply if you spray it on with those Preval handy sprayers (about $7.00) and a little acetone to dilute it. Prep surface by washing and exposing fiberglass. I sand a bit with 150 grit. Clean with Acetone or MEK and let dry. Tape off area to be gelcoated. Mix gelcoat, hardner, and applicable color matching agents. Dilute a bit with Acetone (about 10%). Spray on. Spray or brush on a bit more than the orignal surface level. Cover with monofilm, or spray on PVA mold release (which works especially well over curves, bends or other places the monofilm won't lay on flat). Let dry/harden. When hard, rinse mold release and sand/fair out even with original gelcoat. Use 600 / 1000/ rubbing compound to get it to look good.
These are general ideas. West Marine has a more detailed fact sheet on working with gelcoat on their website.